Ester is the major product formed in the reaction involving an acid anhydride dissolved in alcohol.
What is the chemistry of acid anhydrides?
- Acid chlorides and anhydrides both go through a number of similar reactions when subjected to nucleophilic action.
- Anhydrides react with water to generate carboxylic acids, with alcohols to form esters, and with amines to form amides, though they do so more slowly than acid chlorides.
- By using hydride reduction, anhydrides can also be converted to primary alcohols.
- As many anhydrides are created by coupling two carboxylic acids, one equivalent of the carboxylic acid is lost in anyhydride reactions as a leaving group.
- As a result, reactions are often only carried out using affordable, widely accessible anhydrides, such as acetic or benzoic.
- The advantage of anydrides over acid chlorides is that they are simpler to work with.
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