Heptane is limiting while oxygen is in excess. The mass of carbon dioxide produced would be 9,223.62 grams, while excess oxygen would measure 14,461.12 grams
From the equation of the reaction:
C7H16 + 11O2 --> 7CO2 + 8H2O
Mole ratio of C7H16 to O2 = 1:11
Mole of 3000 g heptane = 3000/100.21
= 29.94 moles
Mole of 25000 g O2 = 25000/32
= 781.25 moles
Thus, O2 is in excess and heptane is limiting.
Mole ratio of heptane and CO2 = 1:7
equivalent mole of CO2 = 29.94 x 7 = 209.58 moles
Mass of 209.58 moles CO2 = 209.58 x 44.01
= 9223.62 grams
Excess mole of O2 = 781.25 - (29.94x11)
= 781.25 - 329.34 = 451.91 moles
Mass of 451.91 moles of O2 = 451.91 x 32
= 14,461.12 grams excess oxygen.
More on stoichiometric calculations can be found here: https://brainly.com/question/8062886