Answer: The molar mass of the vapor comes out to be 43.83 g/mol. This problem is solved by using ideal gas equation. The ideal gas equation is shown below
[tex]\textrm{PV} =\textrm{nRT}[/tex]
Explanation:
Volume of gas = V = 247.3 mL
V = 0.2473 L
Pressure of gas = P = 745 mmHg
1 atm = 760 mmHg
[tex]\textrm{P} = \displaystyle \frac{745}{760} \textrm{ atm} = 0.98026 \textrm{ atm}[/tex]
Temperature of gas = T = 100[tex]^{\circ}C[/tex] = 373 K
Given mass of gas = m = 0.347 g
Assuming molar mass of gas to be M g/mol
Assuming the gas to be an ideal gas, the ideal gas equation is shown below
[tex]\textrm{PV} =\textrm{nRT}[/tex]
Here, n is the number of moles of gas and R is the universal gas constant.
[tex]\textrm{PV} =\textrm{nRT} \\\textrm{PV} = \displaystyle \frac{m}{M}\textrm{RT} \\0.98026 \textrm{ atm}\times 0.2473 \textrm{ L} = \displaystyle \frac{0.347 \textrm{ g}}{M}\times 0.0821 \textrm{ L.atm.mol}^{-1}.K^{-1}\times 373 \textrm{ K} \\M = 43.83 \textrm{ g/mol}[/tex]
Hence, the molar mass of the vapor comes out to be 43.83 g/mol