2NO + O2 → 2NO2
(a) Identify the limiting reactant
From NO:
Moles of NO2 = 6.2 mol NO × (2 mol NO2/2 mol NO) = 6.2 mol NO2
From O2:
Moles of NO2 = 13.0 mol O2 × (2 mol NO2/1 mol O2) = 26.0 mol NO2
The limiting reactant is NO, because it gives fewer moles of product.
∴ Moles of product = 6.2 mol NO2.
(b) Calculate the moles of excess reactant (O2) used
Moles of O2 = 6.2 mol NO × (1 mol O2/2 mol NO) = 3.1 mol NO2
(c) Calculate the moles of unused excess reactant (O2)
Unused = initial – used = 13.0 mol – 3.1 mol = 9.9 mol