To find the average mass of an element you add the mass of each isotope multiplied by it's relative abundance.
[(mass of Cu⁶³)x(relative abundance of Cu⁶³)] + [(mas of Cu⁶⁵)x(relative abundance of Cu⁶⁵0)]= average mass of Cu
[(62.9296)x(.6917)] + [(64.9278)x(.3083)] = 63.54amu