First write a balanced equation...
P4 + 5 O2 ⇒ 2P2O5
mole of P4 = 136 ÷ (4×31) = 1.09677
MOLE RATION OF P4 : P2O5 IS 1:2
THAT IS 1 mole of p4 reacts to give 2 moleof p2o5
∴ 1.09677 mole............................. (2×1.09677) =2.19....mole
maximum number of mole = 2.19 mol