Which sample of water contains particles having the highest average kinetic energy?
(1) 25 mL of water at 95°C
(2) 45 mL of water at 75°C
(3) 75 mL of water at 75°C
(4) 95 mL of water at 25°C
(1) 25 ml of water at 95 degrees Celsius is your answer. Temperature is the average kinetic energy of the substance that it measures, therefore the highest temperature choice, aka #1, is your answer.