The amount of heat needed would be the specific heat multiplied by the mass of the substance and the temperature difference. In this case, the mass would be 75.0–g, the specific heat would be 0.449 j/g °c, and the temperature difference would be 1535 -25= 1510
Then the calculation would be: 0.449 j/g °c * 75g * 1510°c = 50,849.25J
In calorie it would be: 50849.25J / 4.184J/cal= 12,153.26 calorie