The solution of acetic acid in water is represented by this chemcial equation:
CH3COOH + H2O ⇄ H3O+ + CH3COO-
Those are four species:
1) CH3COOH (molecule)
2) H2O (molecule)
3) H3O+ (ion)
4) CH3COOH- (ion)
Given that the solvent is water that is the specie with with the highest concentration.
The solute is CH3COOH so it is the second higher concentration.
Given that CH3COOH is a weak acid the concentration of the products (CH3COO- and H3O+) is low.
And given the stoichiometry the concentration of both species CH3COOH- and H3O+ are equal.
So, the species listed in decreasing order of concentration are:
H2O > CH3COOH > H3O+ , CH3COO-