Respuesta :
Cyclopropane is a highly strained molecule because the conformations of the cycloalkanes are influenced by the torsional, angle strain, and steric strain. Cycloalkanes, which comprises more than three atoms of carbons are not flat molecules, they are puckered.
The three and four-membered ring components exhibit angle strain and minimize the internal bond angles. The angle strain is generated when the bond angles deviate from the optimum tetrahedral angle, that is, 109.5 degree.
Torsional strain is a resultant of eclipsing interactions, and steric strain is attained when the atoms are forced too close to each other.
The cyclopropane molecule is highly strained due to the presence of bond angle 60. Another reason that makes it highly strained is the torsional strain that leads to the formation of eclipsed conformation of the hydrogen bond.
Further explanation:
Cyclopropane is an explosive, colourless gas that is used for medicinal purpose. It is a non-irritating to the mucous membranes and also affects respiration. It is highly strained molecule as the confirmation of cycloalkanes is stimulated by torsional angle, angle strain as well as steric edge.
Cycloalkanes are composed of more than three carbon atoms that are not flat molecule and they are puckered.
The three as well as four-membered ring compound consists of angle strain and also minimise the internal bond angles. Angle strain is formed due to the deviation of bond angles from an optimum tetrahedral angle such as 109.5ᴼ. Torsional stress is formed due to the eclipsing interactions while a steric strain is formed when the carbon atoms are forced towards each other.
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Answer Details:
Grade: Senior School
Subject: Chemistry
Chapter: Organic chemistry
Keywords:
Cycloalkanes, angle strain, torsional strain, puckered, tetrahedral angle, carbon atoms, deviation.
