I think you almost got it.
At the top, the velocity only has horizontal component, so v=12 m/s is v_x, which is v*cos(theta), because v_x is constant, so the same when it was launched or now.
With the value of the initial speed (28 m/s, which is the total speed), you can set
v_x = v * cos( theta ) ---> 12 = 28*cos(theta) --> cos(theta)=12/28=3/7
or theta = 64.62 deg, it is D. Think about it. I hope you see it.