First, examine what happens over the integration domain.
[tex]\displaystyle\frac{\sin^2x}{\sqrt x}=x^{3/2}\frac{\sin^2x}{x^2}\implies\lim_{x\to0^+}x^{3/2}\frac{\sin^2x}{x^2}=0\times1=0[/tex]
[tex]\dfrac{\sin^2x}{\sqrt x}[/tex] is continuous for [tex]x\neq0[/tex], so we don't need to worry about the right endpoint.
Now, note that
[tex]\dfrac{\sin^2x}{\sqrt x}\le\dfrac1{\sqrt x}[/tex]
due to the fact that [tex]|\sin x|\le1\implies0\le\sin^2x\le1[/tex]. So, if the larger integral converges, so must the smaller one. You have
[tex]\displaystyle\int_0^\pi\frac{\mathrm dx}{\sqrt x}=\lim_{t\to0^+}\int_t^\pi x^{-1/2}\,\mathrm dx[/tex]
[tex]=\displaystyle\lim_{t\to0^+}2x^{1/2}\bigg|_{x=t}^{x=\pi}=2\left(\sqrt\pi-\lim_{t\to0^+}\sqrt t\right)=2\sqrt\pi[/tex]
so the larger integral converges. Therefore the smaller one does, too.