The wavelength where the absorbance of the solution is largest is the best choice.
Spectroscopy is based on Beer Lamberts law, where absorbance and transmittance are used to identify the quantity and quality of the sample. The quantitative analysis is utilised for concentration while qualitative analysis is used to identify the functional groups or chemical compounds and occurence or flow of reaction.
The large molar absorptivity is preferred as the minimum sample amount can provide measurable absorbance value. The same is evident from the absorption formula, where molar absorptivity and concentration are inversely proportional.
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