About 95% of any normal distribution falls within two standard deviations of the mean, so 5% falls outside this range with 2.5% to either side. In other words,
[tex]\mathbb P(|Z|<2)=0.95\implies \mathbb P(Z>2)=0.025[/tex]
so that the longest 2.5% fall above two standard deviations from the mean.
The mean for this distribution is 266 and the standard deviation is 256, so two standard deviations above the mean corresponds to [tex]266+2\times256=778[/tex].
So the longest 2.5% of all pregnancies last at least 778 days (which seems ridiculous, since this is a little over 64 years... I assume this is a silly example to get a point across).