A student found that it required 44.7 mL of a 0.1028 M NaOH Solution to neutralize 20.0 mL of an unknown H3PO4 Solution which react according to the equation: 3 NaOH + H3PO4 = Na3PO4 + 3H2O. The molarity of the unknown phosphoric acid solution is:

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ANSWER

The molarity of the unknown phosphoric acid is 0.0762 moles

STEP-BY-STEP EXPLANATION

What to find? The molarity of the unknown phosphoric acid

Given parameters

Volume of base = 44.7mL

Concentration of base = 0.1028 mole

Volume of acid = 20.0mL

nA = 1

nB = 3

To find the concentration of the unknown phosphoric acid, we need to write the balanced equation for the reaction.

[tex]H_3PO_{4(aq)}\text{ + }3NaOH_{(aq)}\text{ }\rightarrow3H_2O_{(l)}\text{ + }Na_3PO_{4(aq)}[/tex]

From the equation of the reaction; This means that 1 mole of H3PO4 neutralizes 3 moles of NaOH

To find the molarity of H3PO4, we will need to apply the below formula

[tex]\frac{C_AV_A}{C_BV_B}\text{ = }\frac{n_A}{n_B}[/tex]

Where;

CA = Concentration of the acid

VA = Volume of acid

CB = Concentration of the base

VB = volume of the base

nA = mole ratio of acid

nB = mole ratio of base

Substitute the parameters into the above formula

[tex]\begin{gathered} \frac{C_{A\cdot\text{ }}20}{0.1028\cdot\text{ 44.7}}\text{ = }\frac{1}{3} \\ Cross\text{ multiply} \\ 3\cdot C_A\cdot\text{ 20 = 0.10208 }\cdot\text{ 44.7 }\cdot\text{ 1} \\ 60C_A\text{ = 4.573184} \\ Divide\text{ both sides by }60 \\ \frac{60C_A}{60\text{ }}\text{ = }\frac{4.573184}{60} \\ C_A\text{ = 0.0762 mole} \end{gathered}[/tex]

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