In order to calculate the potential difference between the plates, we can use the following formula:
[tex]\begin{gathered} Q=\frac{\epsilon_0\cdot A}{d}\cdot\Delta V \\ \sigma\text{ (charge density)}=\frac{Q}{A} \end{gathered}[/tex]Using d = 4 * 10^-3 m, sigma = σ * 10^-12 and ε0 = 8.85 * 10^-12, we have:
[tex]\begin{gathered} \Delta V=\frac{Q\cdot d}{\epsilon_0\cdot A} \\ \Delta V=\frac{\sigma\cdot d}{\epsilon_0} \\ \Delta V=\frac{5\cdot10^{-12}\cdot4\cdot10^{-3}}{8.85\cdot10^{-12}} \\ \Delta V=\frac{20\cdot10^{-3}}{8.85} \\ \Delta V=2.26\text{ mV} \end{gathered}[/tex]Therefore the correct option is the third one.