what are the two 45 degree angles called?example.. vertical, alternate interior, ect...I know the two middle are the vertical

Consider that angles D and C are alternate interior angles.
Similarly, angles A and E are alternate interior angles.
And since the alternate interior angles made by a transversal over two parallel lines are always equal, it follows that,
[tex]\begin{gathered} \angle D=\angle C \\ \angle A=\angle E \end{gathered}[/tex]But there is no direct relation between the angles E and C.