The reaction of combustion of octane is as follows:
[tex]2C_8H_{18}+25O_2\rightarrow16CO_2+18H_2O[/tex]Convert the given mass of octane to moles using the molar mass of octane:
[tex]90.0g\cdot\frac{mol}{114.23g}=0.79mol[/tex]According to the given reaction, 2 moles of octane produce 18 moles of water. Use this ratio to find how many moles of water are produced from 0.79 moles of octane:
[tex]0.79molC_8H_{18}\cdot\frac{18molH_2O}{2molC_8H_{18}}=7.11molH_2O[/tex]Multiply this amount times the efficiency of the reaction to find the actual amount of water produced:
[tex]7.11molH_2O\cdot74.3\%=5.28molH_2O[/tex]Convert this amount to moles using the molar mass of water:
[tex]5.28molH_2O\cdot\frac{18g}{molH_2O}=95.04g[/tex]It means that the mass of water produced is 95.04g.