The wavelength of the monochromatic beam is given as,
[tex]\lambda=605\text{ nm}[/tex]The value of the width of the slit is,
[tex]d=0.095\text{ mm}[/tex]The distance of the slit from the screen is,
[tex]D=85\text{ cm}[/tex]Thus, the distance of the dark band from the center is,
[tex]y=\frac{(2m+1)\lambda D}{d}[/tex]For the first dark band,
m=0,
Substituting all the known values,
The value of the distance of the dark band becomes,
[tex]\begin{gathered} y=\frac{605\times10^{-9}\times85\times10^{-2}}{0.095\times10^{-3}} \\ y=540000\times10^{-8}\text{ m} \\ y=5.4\text{ mm} \end{gathered}[/tex]Thus, the first dark band is 5.4 mm away from the center of the screen.
Hence, the correct answer is 5.4 mm.