A 1.0857 gram pure sample of a compound containing only carbon, hydrogen, and oxygen was burned in excess oxygen gas. 3.190 g of carbon dioxide and 0.9360g of water were produced. find the empirical formula of the compound.

Respuesta :

The empirical formula of the compound will be C₁₂ H₁₈ O

1) Mass of carbon (C) in 3.190 g of carbon dioxide (CO₂)

  • atomic mass of C: 12.0107 g/mol
  • molar mass of CO₂: 44.01 g/mol

Proportion: 12.0107 g of C / 44.01 g of CO₂ = x / 3.190 g of CO₂

Solving for x:

x = (12.0107 g of C / 44.01 g of CO₂ ) × 3.190 g of CO₂ = 0.87053 g of C

2) Mass of hydrogen (H) in 0.9360 g of water (H₂O)

  • atomic mass of H: 1.00784 g/mol
  • molar mass of H₂O: 18.01528 g/mol

Proportion: 2 × 1.00784 g of H / 18.01528 g of H₂O = x / 0.9360 g of H₂O

Solving for x:

x = ( 2 × 1.00784 g of H / 18.01528 g of H₂O) × 0.9360 g of H₂O = 0.10472 g of H

3) Mass of oxygen (O) in 1.0857 g of pure sample

Mass of O = mass of pure sample - mass of C - mass of H

Mass of O = 1.0857 g - 0.87053 g - 0.10472 = 0.09392 g O

Round to four decimals: Mass of O = 0.0939 g

4) Mole calculations

Dividing the mass in grams of each element by its atomic mass:

C: 0.87053 g / 12.0107 g/mol = 0.07247 mol

H: 0.10472 g / 1.00784 g/mol = 0.10390 mol

O: 0.0939 g / 15.999 g/mol = 0.00586 mol

5) Dividing every amount by the smallest value to find the mole ratios :

C: 0.07247 mol / 0.00586 mol = 12.36 ≈ 12

H: 0.10390 mol / 0.00586 mol = 17.7 ≈ 18

O: 0.00586 mol / 0.00586 mol = 1

Thus the mole ratio is 12 : 18 : 1, and the empirical formula is:

C₁₂ H₁₈ O

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