In a mass spectrometer, the ion with the highest abundance in the mass spectrum that is assigned a relative abundance of 100% is referred to as the base peak.
The base peak is the greatest peak in the mass spectrum that corresponds to the most prevalent ion or the strongest peak in the spectrum. It could be the parent peak or a fragment ion peak, depending on the type of molecule. Sometimes the base peak may be the molecular ion peak.
The base peak, which is the peak with the highest intensity in the spectrum, is given a value of 100 percent, and the intensities of the other peaks, including the molecular ion peak, are expressed as a percentage of the base peak (height x sensitivity factor). In addition to producing positive ions, bombarding a sample with electrons can also produce negative ions.
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