The liquid with the highest vapor pressure is a medium-sized puddle of spilled hot water because vapor pressure depends on temperature.
The vapor pressure of a liquid is the pressure of the liquid due to the vapor of the liquid in contact with the surface of the liquid.
Vapor pressure does not depend on the volume or mass of the liquid bit on the composition and temperature of the liquid.
Therefore, the liquid with the highest vapor pressure is a medium-sized puddle of spilled hot water because vapor pressure depends on temperature.
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