A complex is a compound that is composed of a central metal atom/ion and then ligands. MnO4- is a d^0 specie hence it has no d electron.
A complex is a compound that is composed of a central metal atom/ion and then ligands. These ligands may lead to the color of the complex. However, the color of complexes more commonly result from the d-orbital transition in the metal atom/ion.
Now we know that the neutral electron configuration of Mn is [Ar]. 3d5. 4s2. It then follows that MnO4- is a d^0 specie hence it has no d electron.
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