Based on the law of conservation of heat;
- Heat losses in a calorimeter will lower the value of enthalpy change, ΔH, for a particular reaction.
- An error in the volume of one of the reacting solutions will increase the heat generated, the ΔT observed, the q calculated, and the calculated ΔH.
- Using a wet Styrofoam cup will lower the heat generated, the ΔT observed, the q calculated, and the calculated ΔH.
What is a calorimeter?
A calorimeter is a laboratory apparatus used to measure heat changes that occur in a reaction.
A calorimeter works on the principle of conservation of heat which can be stated as;
- Heat lost by hotter body = Heat gained by colder body.
The formula for calculating quantity of heat, q is given as;
where
- m is mass of substance
- c is heat capacity of substance
- θ is temperature change
Heat losses in a calorimeter will lower the value of enthalpy change, ΔH, for a particular reaction.
Error in the volume of substances used will affect the value of the heat generated, the ΔT observed, the q calculated, and the Δ H calculated as follows:
- the heat generated will increase
- the ΔT observed will increase
- the value of q will increase
- the value of ΔH will increase
If the calorimeter used, (Styrofoam cup) is wet when used, the volume of the liquid to be heated will be higher. Therefore, the heat generated, the ΔT observed, the q calculated, and the calculated ΔH will be affected as follows:
- the heat generated will decrease
- ΔT observed will be lower
- the value of q will decrease
- the value of ΔH will increase
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