Reaction three is the single replacement reaction.
A single displacement or replacement reactions are the exchange of a single element with another compound or element.
The first reaction is a combination reaction as the water and oxygen combines togetherly to produce hydrogen peroxide and hence is incorrect.
The second reaction is a decomposition reaction in which the reactant [tex]\rm Al_{2}S_{3}[/tex] breaks into two products [tex]\rm 2Al[/tex] and [tex]3\rm S[/tex].
The third reaction is the single replacement reaction as more reactive [tex]\rm Cl_{2}[/tex] displaces [tex]\rm Br[/tex] from the potassium to produce [tex]\rm 2KCl[/tex] and [tex]\rm Br_{2}[/tex].
The fourth reaction is a combustion reaction as hydrocarbon reacts with the oxygen molecule to produce water and carbon dioxide.
Therefore, [tex]\rm Al_{2}S_{3} \rightarrow2Al + 3S[/tex] is the single-displacement reaction.
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