Question

Explain how electrostatic attraction affects the van’t Hoff factor. Why is the effect always to lower the van’t Hoff factor from the simple assumption that dissolved ionic substances always form whole number values of ions?

Answer 1

Van't Hoff factor is being affected by electrostatic attraction as the solute concentration increases, thereby decreasing van't Hoff factor.

The van't Hoff factor is therefore becomes a measure of a deviation from ideal behavior. In order words, the lower the van 't Hoff factor, the greater the deviation.

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