The double bonds in CO2 are counted as single regions of electron density.
The valence shell electron pair repulsion theory VSEPR is a description of the shape of molecules based on the number of electron pairs that surround the central atom in the molecule. Double bonds are counted as a single region of electron density.
Hence, the two double bonds in CO2 are counted as two regions of electron density around the central carbon atom. Hence, the molecule is liner at a bond angle of 180 degrees.
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