Estimate under what set of conditions it is possible, despite the spherical shape of the working electrode, to use linear diffusion equations to theoretically predict the current vs voltage curve expected in this experiment.

When the experimental measurements diverge at very low values of the voltages. When the ratio of current to saturated current is very small. That is, i/I less than or equal to 1/100. When there is a finite current at Voltage

V = 0

Diffusion will have influence on current - voltage curve in the working electrode which is ionization detector.

The estimation under set of conditions that is possible, despite the spherical shape of the working electrode, to use linear diffusion equations to theoretically predict the current vs voltage curve expected in this experiment will be:

When the experimental measurements diverge at very low values of the voltages
when the ratio of current to saturated current is very small. That is, i/I less than or equal to 1/100
When there is a finite current at Voltage V = 0

Where

i = electric current

I = saturated current

V = voltage supplied

The curve expected will therefore give exponential curve from positive to negative domain because of the diffusion of ions from different directions

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