Answer:
• Molar mass of caffeine:
[tex] = { \rm{(12 \times 3) + (1\times 60) + (14 \times 4) + (16 \times 2)}} \\ \\ = { \rm{194 \: g}}[/tex]
• From avogadro's number:
[tex]{ \rm{134 \: g \: \dashrightarrow \: 6.02 \times {10}^{23} \: atoms}} \\ { \rm{34.5 \: g \: \dashrightarrow \: ( \frac{34.5}{194} \times 6.02 \times {10}^{23}) \: atoms }} \\ \\{ \boxed { \rm{ = 1.08 \times {10}^{23} \: atoms}}}[/tex]