Consider the k-th partial sum,
[tex]S_k = 1 + \dfrac2\pi + \dfrac3{\pi^2} + \cdots + \dfrac k{\pi^{k-1}}[/tex]
More compactly,
[tex]\displaystyle S_k = \sum_{i=1}^k \frac i{\pi^{i-1}} = \frac{(1-\pi)k+\pi^{k+1}-\pi}{(1-\pi)^2\pi^{k-1}}[/tex]
(this is just another case of a similar sum you asked about a while ago [24494877])
The infinite sum is the limit of the partial sum as k goes to infinity. We have
[tex]\displaystyle \lim_{k\to\infty} \frac{(1-\pi)k+\pi^{k+1}-\pi}{(1-\pi)^2\pi^{k-1}} = \frac\pi{(1-\pi)^2} \lim_{k\to\infty} \left(\frac{(1-\pi)k}{\pi^k} + \pi - \frac1{\pi^{k-1}} \right) = \boxed{\frac{\pi^2}{(1-\pi)^2}}[/tex]
since the non-constant terms in the limit converge to 0.
Alternatively, recall that for |x| < 1, we have
[tex]\dfrac1{1-x} = \displaystyle \sum_{n=0}^\infty x^n[/tex]
Differentiating both sides gives
[tex]\dfrac1{(1-x)^2} = \displaystyle \sum_{n=0}^\infty nx^{n-1} = \sum_{n=1}^\infty nx^{n-1}[/tex]
also valid for |x| < 1. Take x = 1/π and you get the sum you want to compute.