As the system approaches equilibrium, entropy is near its maximum.
The entropy is said to be the degree of disorderliness of a system. Ice is a crystal in which the molecules are perfectly ordered so its entropy is at a minimum.
As ice melts, the molecules gain more energy and separate from each other. There is now an increase of particles in the system leading to an increase in entropy.
Hence, when the system is at equilibrium, entropy is at a maximum.
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