Question

What is the AHsol for LiF → Lit + F-? The lattice energy is -1,036 kJ/
mol, the enthalpy of hydration for Lit is -499
kJ/mol, and the enthalpy of hydration for F-is-431 kJ/mol. Use A Hooi = -A Hat + AHhydr.
0-968 kJ/mol
-106 kJ/mol
106 kJ/mol
1,966 kJ/
mol

Answer 1

The heat of hydration is defined as the heat absorbed or evolved when one mole of a substance undergoes hydration. The heat of solution is the enthalpy change associated with he dissolution of a solute. The lattice energy is the heat. Lattice energy is the energy released when the components of the lattice are brought together from infinity.

Hence the heat of solution for LiF → Li^+ + F- is -1966  kJ/mol

Given that;

Heat of hydration = ΔH solution – ΔH lattice energy

Where,

ΔH solution  = Heat of the solution

ΔH lattice energy = Lattice energy of the solution

The heat of solution or enthalpy of dissolution is defined as the enthalpy change associated with the dissolution of a solute in a solvent

From the formula above;

ΔH solution = Heat of hydration + ΔH lattice energy

Heat of hydration = [(-431) + (-499)] = -930 kJ/mol

ΔH solution = (-930) + (-1,036) = -1966  kJ/mol

Hence the heat of solution for LiF → Li^+ + F- is -1966  kJ/mol

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