n moles of CO2 gas (T1, V1) obey a van der Waals equation of state are contained in an insulated piston-cylinder arrangement. A reversible expansion of the gas is carried out until the volume become 2V1.
[CV.m = 28.80 J mol−1K−1, a = 3.610 atm. dm6. mol−2, b = 4.29 x 10−2 dm3. mol−1]
(a) Find the final temperature of gas as a function of n, . , T1, V1 and the van
der Waals parameter a and b.
(b) If two moles of CO2 gas involved and T1 = 350K, V1 = 40L, compute final
temperature of the gas.
(c) Find work done and internal energy of the gas.

Respuesta :

Answer:

one or two three or four

Explanation:

animals of CO2 gas find the final temperature of gas

The final temperature of the 2 moles of gas has been 0.0014 K.

The gas has been assumed to be the ideal gas. The moles of the has been n. According to the ideal gas equation:

(a) PV= nRT.

For the reversible expansion of 1 mole of gas:

P = [tex]\rm \dfrac{RT}{V - b}\;\times\;\dfrac{a}{V^2}[/tex]

For n moles of gas, the reversible expansion will be:

P = [tex]\rm \dfrac{nRT}{V - b}\;\times\;\dfrac{a}{V^2}[/tex]

The final temperature of the reversible expansion has been:

[tex]\rm T_f\;=\;T_i\;+\;\dfrac{an^2\;[\frac{1}{Vf\;-\;\frac{1}{Vi} } ]}{Cv}[/tex]

(B) The ideal gas equation can be given as:

[tex]\rm \dfrac{P1V1}{nT1}\;=\; \dfrac{P2V2}{nT2}[/tex]

Substituting the values:

[tex]\rm \dfrac{40}{2\;\times\;350}\;=\;\dfrac{80}{2\;\times\;T2}[/tex]

T2 = 0.0014 K.

The final temperature of the 2 moles of gas has been 0.0014 K.

(c) The work done can be given by:

W = nRT In[tex]\rm \dfrac{V2}{V1}[/tex]

The internal energy of the system has been given by:

[tex]\Delta[/tex]U = [tex]\rm C_v[/tex][[tex]\rm T_f\;-\;T_i[/tex]] - a[tex]\rm n^2[/tex] [tex]\rm [\dfrac{1}{Vf}\;-\;\dfrac{1}{Vi} ][/tex]

For more information about the reversible expansion of gas, refer to the link:

https://brainly.com/question/22791115

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