The calorimeter is used to measure the heat of the system. The enthalpy of the combustion of magnesium cannot be measured by the calorimeter as it could melt the cup.
What is a coffee cup calorimeter?
A coffee cup calorimeter is a styrofoam cup that contains partially filled water and is dipped with a thermometer. The reaction occurs in the water of the cup and hence differs from the bomb calorimeter.
The enthalpy of combustion is rigorous which can dissolve the polystyrene cup and hence is not used. They are better insulators than a beaker. The coffee cup calorimeter is not used to measure the enthalpy of hydrogen and oxygen as they involve gases that can escape the cup.
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