Respuesta :

Answer: 169.3 g of [tex]AlCl_3[/tex] will be produced

Explanation:

To calculate the moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text {Molar mass}}[/tex]

moles of [tex]Al[/tex]

[tex]\text{Number of moles}=\frac{50.0g}{27g/mol}=1.85moles[/tex]

moles of [tex]Cl_2[/tex]

According to ideal gas equation:

[tex]PV=nRT[/tex]

P = pressure of gas = 1 atm (STP)  

V = Volume of gas = 42.7 L

n = number of moles = ?

R = gas constant =[tex]0.0821Latm/Kmol[/tex]

T =temperature =[tex]273K[/tex]   (at STP)

[tex]n=\frac{PV}{RT}[/tex]

[tex]n=\frac{1atm\times 42.7L}{0.0820 L atm/K mol\times 273K}=1.90moles[/tex]

[tex]2Al+3Cl_2\rightarrow 2AlCl_3[/tex]

According to stoichiometry:

3 moles of [tex]Cl_2[/tex] reacts with = 2 moles of aluminium

Thus 1.90 moles of [tex]Cl_2[/tex]reacts with=  [tex]\frac{2}{3}\times 1.90=1.27[/tex] moles of aluminium  

Thus [tex]Cl_2[/tex] is the limiting reagent as it limits the formation of product.

As 3 moles of [tex]Cl_2[/tex] give =  2 moles of [tex]AlCl_3[/tex]

Thus 1.90 moles of [tex]Cl_2[/tex] give =[tex]\frac{2}{3}\times 1.90=1.27moles[/tex]  of [tex]AlCl_3[/tex]

Mass of [tex]AlCl_3=moles\times {\text {Molar mass}}=1.27moles\times 133.34g/mol=169.3g[/tex]

Thus 169.3 g of [tex]AlCl_3[/tex] will be produced from the given masses of both reactants.

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