Answer:
a. 0.20 M HF and 0.10 M NaOH.
c. 0.10 M HF and 0.10 M NaF
d. 0.10 M HCl and 0.20 M NaF.
Explanation:
A buffer solution consists of a weak acid and its conjugate base, or of a weak base and its conjugate acid.
In this case, HF is the weak acid and F⁻ is its conjugate base.
Let's go case-by-case:
a. 0.20 M HF and 0.10 M NaOH.
b. 0.10 M HF and 0.10 M NaOH.
c. 0.10 M HF and 0.10 M NaF.
d. 0.10 M HCl and 0.20 M NaF.
The correct answers are A), C) and D).