You only need to count the number of atoms of each element in both sides of the equation. To be balanced, the number of each kind of atom has to be equal in the two sides.
Only the fourth equation, 2PbS + 3O2→ 2PbO + 2SO2, complies that:
Element Left side Right side
Pb 2 2
S 2 2
O 3*2=6 2 + 2*2 = 2 + 4 = 6