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The role that Monte Albán play in the development of cities in Mesoamerica is that it has become the earliest evidence of calendar use in Mesoamerica. Thank you for posting your question. I hope this answer helped you. Let me know if you need more help. 

The correct answer is C) it was considered the largest socio-political and economic center in Mesoamerica for Approximately 600 years.

The role that Monte Albán played in the development of cities in Mesoamerica was "it was considered the largest socio-political and economic center in Mesoamerica for Approximately 600 years."

The Zapotecs had an impressive capital city: Monte Alban. Archeologists think that it was founded in 500 BC. It is located in Oaxaca City, Mexico, and it was considered the largest socio-political and economic center in Mesoamerica for Approximately 600 years. The Monte Alban archeological center is extremely well conserved by Mexican authorities and can be visited any day of the year.

The other options of the question were A) it began bartering with neighboring cities, which started the early beginnings of trade in the region. B) it established the first Roman Catholic settlement. C) it was the first city constructed with aqueducts, which provided future cities with waterway systems.