in equilibrium the initial concentration of hydrogen and bromine is 0.50mol/L what is the equilibrium concentration of hydrogen bromide ( H2 + Br2 <> 2HBr ) kc= 50.0

Respuesta :

Answer:

The concentration of HBr at the equilibrium is   0.780 M

Explanation:

Step 1: Data given

The initial concentration of H2 = 0.50 mol/L

The initial concentration of Br2 = 0.50 mol/L

Kc = 50.0

Step 2: The balanced equation

H2 + Br2 ⇆ 2HBr

Step 3: The concentration at equilibrium

[H2] = 0.50 - X M

[Br2] = 0.50 - X M

[HBr] = 2X

Step 4: Calculate concentration of HBr

Kc = [HBr]² [H2][Br2]

50.0 = 4X² / (0.50 - X)(0.50 -X)

X = 0.390

[H2] = 0.50 - 0.390 = 0.110 M

[Br2] = 0.50 - 0.390 = 0.110 M

[HBr] = 2*0.390 = 0.780 M

Answer:

[tex][HBr]_{eq}=0.78M[/tex]

Explanation:

Hello,

In this case, the undergoing chemical reaction is:

[tex]H_2 + Br_2 \rightleftharpoons 2HBr[/tex]

In that way, the Law of mass action results:

[tex]Kc=\frac{[HBr]^2}{[H_2][Br_2]}[/tex]

Hence, in terms of the change [tex]x[/tex] due to the reaction extent, we obtain:

[tex]50.0=\frac{(2x)^2}{(0.5M-x)(0.5M-x)}[/tex]

In such a way, by solving via the quadratic equation (two results), the results are:

[tex]x_1=0.390M\\x_2=0.697M[/tex]

But the correct one is 0.390M as the other one results in negative concentrations of hydrogen and bromine at equilibrium. Therefore, the concentration of hydrogen bromide results:

[tex][HBr]_{eq}=2x=2*0.390M[/tex]

[tex][HBr]_{eq}=0.78M[/tex]

Best regards.

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