The steps in a reaction mechanism are as follows. Which species is acting as a catalyst? Step 1: Ag+(aq) + Ce4+(aq) <-----> Ag2+(aq) + Ce3+(aq) Step 2: Tl+(aq) + Ag2+(aq) -----> Tl2+(aq) + Ag+(aq) Step 3: Tl2+(aq) + Ce4+(aq) -----> Tl3+(aq) + Ce3+(aq)

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Answer:

Ag⁺ acts as the catalyst.

Explanation:

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In this case, each step is reorganized:

- Step 1:

[tex]Ag^+(aq) + Ce^{4+}(aq) \rightleftharpoons Ag^{2+}(aq) + Ce^{3+}(aq)[/tex]

- Step 2:

[tex]Tl^+(aq) + Ag^{2+}(aq) \rightarrow Tl^{2+}(aq) + Ag^+(aq)[/tex]

- Step 3:

[tex]Tl^{2+}(aq) + Ce^{4+}(aq) \longrightarrow Tl^{3+}(aq) + Ce^{3+}(aq)[/tex]

In such a way, Ag⁺ is converted to Ag²⁺ in the first step, but then it is regenerated to simple Ag⁺, therefore, Ag⁺ acts as the catalyst.

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The specie which is acting as a catalyst is; Ag+(aq).

Discussion:

The catalyst is a specie that exists in the same form at the beginning and end of the reaction.

The reaction's mechanism is as follows;

  • Step 1: Ag+(aq) + Ce⁴+(aq) <-----> Ag²+(aq) + Ce³+(aq)

  • Step 2: Tl+(aq) + Ag²+(aq) -----> Tl²+(aq) + Ag+(aq)

  • Step 3: Tl²+(aq) + Ce⁴+(aq) -----> Tl³+(aq) + Ce³+(aq)

Evidently, although Ag+(aq) was converted to Ag²+(aq) in Step 1 of the reaction; the Ag²+(aq) is reverted back to Ag+(aq) in Step 2 of the reaction.

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