1.0 LL of a buffer is prepared. It contains 0.125 M HAM HA (pKapKa = 4.74) and 0.115 M A−M A−. What is the pH of this buffer after 0.0100 molmol of strong acid is added?

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Answer:

pH of buffer before addition of Strong acid = 4.71

pH of buffer after addition of Strong acid = 2

Explanation:

According to Henderson's equation

⇒pH = pKa +㏒[tex]\frac{[salt]}{[Acid]}[/tex]

⇒pH = 4.74 + log([tex]\frac{0.115}{0.12}[/tex])

⇒pH = 4.74 - 0.03

pH = 4.71

⇒[H⁺] = 1.9 x 10⁻⁵

pH of this buffer after 0.01 mole of strong acid addition

⇒pH = - log[H⁺]

⇒pH = - log(1.9 x 10⁻⁵ + 0.01)

pH = 2

pH of buffer before addition of Strong acid = 4.71

pH of buffer after addition of Strong acid = 2

According to Henderson's equation:

pH = pKa + log ([salt]/ [acid])

pH = 4.74 + log (0.115/0.12)

pH = 4.74 - 0.03

pH = 4.71

[H⁺] = 1.9 x 10⁻⁵

pH of this buffer after 0.01 mole of strong acid addition:

pH = - log[H⁺]

pH = - log(1.9 x 10⁻⁵ + 0.01)

pH = 2

Thus,

pH of buffer before addition of Strong acid = 4.71

pH of buffer after addition of Strong acid = 2

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