The rate at which a certain Australian tree cricket chirps is 194/min at 28°C, but only 47.6/min at 5°C, From these data calculate the energy of activation for the chirping process. (Hint: the ratio of the rates is equal to the ratio of the rate constants.) Enter in units of kJ/mol.

Respuesta :

Answer: The energy of activation for the chirping process is 283.911 kJ/mol

Explanation:

According to the Arrhenius equation,

[tex]K=A\times e^{\frac{-Ea}{RT}}[/tex]

The expression used with catalyst and without catalyst is,

[tex]\log (\frac{K_2}{K_1})=\frac{Ea}{2.303\times R}[\frac{1}{T_1}-\frac{1}{T_2}][/tex]

where,

[tex]K_2[/tex] = rate of reaction at [tex]28^0C[/tex] = 194/min

[tex]K_1[/tex] = rate of reaction at  [tex]5^0C[/tex] = 47.6 /min

[tex]Ea[/tex] = activation energy

R = gas constant = 8.314 J/Kmol

tex]T_1[/tex] = initial temperature = [tex]5^oC=273+5=278K[/tex]

tex]T_1[/tex] = final temperature = [tex]28^oC=273+28=301K[/tex]

Now put all the given values in this formula, we get

[tex]\frac{194}{47.6}=\frac{E_a}{2.303\times 8.314}[\frac{1}{278}-\frac{1}{301}][/tex]

[tex]{E_a}=283911J/mol=283.911kJ/mol[/tex]

Thus the energy of activation for the chirping process is 283.911 kJ/mol

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