Gas at a temperature of 250°C with a convective coefficient 75 W/m2·K flows through a packed bed of aluminum (2024) spheres that is used as a thermal energy storage system. If the initial temperature of the spheres is 25°C and the diameter of each sphere is 75-mm, find the time, in seconds, required to for a sphere to reach 85% of the maximum possible thermal energy as well as the surface temperature and the centerline temperature at this time, both in °C. Evaluate the properties of the aluminum (2024) at 500 K.