If [tex]n[/tex] is odd, then we can write [tex]n=2m+1[/tex] for some [tex]m\in Bbb Z[/tex].
Expanding gives
[tex]n^4=(2m+1)^4=16m^4+32m^3+24m^2+8m+1[/tex]
This reduces to
[tex]n^4\equiv8m^2+8m+1\pmod{16}[/tex]
Notice that [tex]8m^2+8m=8m(m+1)[/tex] is 8 times the product of two consecutive integers, one even and the other odd. This product is even and thus divisible by 2, so that [tex]8m^2+8m=16\ell[/tex] where [tex]\ell\in\Bbb Z[/tex], and the equivalence further reduces to
[tex]n^4\equiv16\ell+1\equiv1\pmod{16}[/tex]
as required.