Respuesta :
Answer:
[CICH2COOH] = 0.089 M
[CICH2COO-] = 0.011 M
[H+] = 0.011 M
Ka = 1.36 x 10^-3
Explanation:
The reaction
CICH2COOH ⇄ H+ (aq) + CICH2COO- (aq)
The initial concentration of CICH2COOH is 0.10 M , chloroacetic acid is 11.0% ionized.
let us calculate Ka
First , find change in concentration
since , 11% ionized
change in concentration = 0.10 X 11% = 0.011 M
Initial Concentration of CICH2COOH = 0.10 M
change in concentration of CICH2COOH = - 0.011 M
Equilibrium Concentration of CICH2COOH = 0.10 M - 0.011 M = 0.089 m
Initial Concentration of CICH2COO- = 0 M
change in concentration of CICH2COO- = + 0.011 M
Equilibrium Concentration of CICH2COO- = 0.011 M
Initial Concentration of H+ = 0 M
change in concentration of H+ = + 0.011 M
Equilibrium Concentration of H+ = 0.011 M
Therefore,
[CICH2COOH] = 0.089 M
[CICH2COO-] = 0.011 M
[H+] = 0.011 M
Ka = [H+][CICH2COO-] /[CICH2COOH]
Ka = (0.011 * 0.011) / (0.089)
Ka = 1.36 x 10^-3
From the formula for the percentage ionization of acid, the acid dissociation constant is 1.21* 10^-3.
What is percent ionization?
The term percent ionization shows the extent to which the acid have been converted to ionic species in solution.
But we know that;
α=√Ka/C * 100
Where;
α= percent ionization
Ka = dissociation constant of acid
C = concentration of acid
Hence;
11 = √Ka/0.100 * 100
11/100 = √Ka/0.100
(11/100)^2 = Ka/0.100
Ka = 0.100 (11/100)^2
Ka = 1.21* 10^-3
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