Some hydrogen gas is enclosed within a chamber being held at 200^\ { C} with a volume of 0.025 \rm m^3. The chamber is fitted with a movable piston. Initially, the pressure in the gas is 1.50 \times 10^6 \; \rm Pa (14.8 \rm atm). The piston is slowly extracted until the pressure in the gas falls to 0.950 \times 10^6 \; \rm Pa. What is the final volume V_2 of the container? Assume that no gas escapes and that the temperature remains at 200^ { C}.

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Answer:

The final volume is [tex] 0.039 m^3[/tex]

Explanation:

Data:

Initial temperature: [tex]T1=200C [/tex]

Final temperature: [tex]T2=200C [/tex]

Initial pressure: [tex] P1=1.50 \times10^6 Pa[/tex]

Final pressure: [tex] P2=0.950 \times10^6 Pa[/tex]

Initial volume: [tex]V1=0.025m^{3} [/tex]

Final volume: [tex] V2=?[/tex]

Assuming hydrogen gas as a perfect gas it satisfies the perfect gas equation:

[tex] \frac{PV}{T}=nR [/tex] (1)

With P the pressure, V the volume, T the temperature, R the perfect gas constant and n the number of moles. If no gas escapes the number of moles of the gas remain constant so the right side of equation (1) is a constant, that allows to equate:

[tex]\frac{P_{1}V_{1}}{T_{1}}=\frac{P_{2}V_{2}}{T_{2}} [/tex]

Subscript 2 referring to final state and 1 to initial state.

solving for V2:

[tex]V_{2}=\frac{P_{1}V_{1}T_{2}}{T_{1}P_{2}}=\frac{(1.50 \times10^6)(0.025)(200)}{(200)(0.950 \times10^6)} [/tex]

[tex] V_{2}=0.039 m^3[/tex]

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