Answer:
No, I wouldn't trade.
Explanation:
Originally there were 6 envelopes with money, so both my friend and I had equal chances (1/6) of getting X amount of money.
Since I got $16, that means that out of the remaining 5 possibilities, only 2 of them contain an amount higher than $16. And one of those possibilities is $64 which is the highest possible amount. If my friend has $64 in his envelope, he will definitely not trade, so that eliminates the $64 possibility.
The only four possibilities left are $2, $4, $8, and $32. Only one of them is higher than $16, while three are lower. So the chance that I get less than $16 is 3/4 or 75%.