A welder using a tank of volume 7.60×10−2 m3 fills it with oxygen (with a molar mass of 32.0 g/mol ) at a gauge pressure of 3.05×105 Pa and temperature of 35.4 ∘C. The tank has a small leak, and in time some of the oxygen leaks out. On a day when the temperature is 20.8 ∘C, the gauge pressure of the oxygen in the tank is 1.95×105 Pa.Find the initial mass of oxygen. (in Kg)

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Answer:

The initial mass of oxygen is 0.38538 Kg.

Explanation:

Given that,

Volume of tank [tex]V= 7.60\times10^{-2}\ m^3[/tex]

Molar mass = 32.0 g/mol

Gauge pressure [tex]P_{g}=3.05\times10^{5}\ pa[/tex]

Initial temperature = 35.4°C

Final temperature = 20.8°C

Gauge pressure [tex]P_{g}=1.95\times10^{5}\ Pa[/tex]

We need to calculate initial pressure

Using formula of pressure

[tex]P_{1}=P_{atm}+P_{g}[/tex]

Put the value into the formula

[tex]P_{1}=1.013\times10^{5}+3.05\times10^{5}[/tex]

[tex]P_{1}=4.063\times10^{5}\ Pa[/tex]

We need to calculate the number of moles

Using equation of ideal gas

[tex]PV= nRT[/tex]

[tex]n_{i}=\dfrac{P_{1}V_{1}}{RT_{1}}[/tex]

Put the value into the formula

[tex]n_{i}=\dfrac{4.063\times10^{5}\times7.60\times10^{-2}}{8.314\times(273+35.4)}[/tex]

[tex]n_{i}=12.043\ moles[/tex]

We need to calculate the initial mass of oxygen

Using formula of mass

[tex]M=m_{m}n_{i}[/tex]

Put the value into the formula

[tex]M=32.0\times12.043[/tex]

[tex]M=385.38\ g[/tex]

[tex]M=0.38538\ kg[/tex]

Hence, The initial mass of oxygen is 0.38538 Kg.

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