Diatomic iodine [I2] decomposes at high temperature to form I atoms according to the reaction I2(g)⇌2I(g), Kc = 0.011 at 1200∘C In an equilibrium mixture, the concentration of I2 is 0.10 M. What is the equilibrium concentration of I? Express your answer using two significant figures.

Respuesta :

Answer:

The concentration of I at equilibrium = 3.3166×10⁻² M

Explanation:

For the equilibrium reaction,

I₂ (g) ⇄ 2I (g)

The expression for Kc for the reaction is:

[tex]K_c=\frac {\left[I_{Equilibrium} \right]^2}{\left[I_2_{Equilibrium} \right]}[/tex]

Given:

[tex]\left[I_2_{Equilibrium} \right][/tex] = 0.10 M

Kc = 0.011

Applying in the above formula to find the equilibrium concentration of I as:

[tex]0.011=\frac {\left[I_{Equilibrium} \right]^2}{0.10}[/tex]

So,

[tex]\left[I_{Equilibrium} \right]^2=0.011\times 0.10[/tex]

[tex]\left[I_{Equilibrium} \right]^2=0.0011[/tex]

[tex]\left[I_{Equilibrium} \right]=3.3166\times 10^{-2}\ M[/tex]

Thus, The concentration of I at equilibrium = 3.3166×10⁻² M

A chemical reaction where the reactant splits into two more products is called a decomposition reaction. The decomposed iodine will have a concentration of [tex]3.3166 \times10^{-2} \;\rm M[/tex] at equilibrium.

What is the equilibrium constant for concentration?

The equilibrium constant for concentration [tex]\rm (K_{c})[/tex] is the proportion of the balanced concentrations of products with the reactants and their powers of stoichiometry.

The equilibrium reaction of decomposition can be shown as:

[tex]\rm I_{2} (g) \rightleftharpoons 2I (g)[/tex]

The equation for the [tex]\rm (K_{c})[/tex] is:

[tex]\rm K_{c} = \dfrac{[I]^{2}}{[I_{2}]}[/tex]

Given,

  • Equilibrium concentration of [tex]\rm I_{2}[/tex] = 0.10 M
  • Equilibrium constant [tex](\rm K_{c})[/tex] = 0.011

Substituting values in the above equation:

[tex]\begin{aligned}0.011 &= \dfrac{[\rm I]^{2}}{0.10}\\\\\rm [I_{\rm equilibrium}]^{2}&= 0.011 \times 0.10\\\\&= 3.31 \times 10^{-2} \;\rm M\end{aligned}[/tex]

Therefore, the concentration of I at equilibrium is [tex]3.3166 \times10^{-2} \;\rm M[/tex] .

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