The enthalpy of reaction for the decomposition of ammonium nitrate, NH4NO3 is -77.4 kJ mol^-1. Calculate the heat evolved when 78.8 g of water is formed from this reaction. Given: NH4NO3 (S)—> N2O+ 2H2O (g)

Answer:
- 169.42 kJ.
Explanation:
n = mass/molar mass.
∴ n of H₂O = mass/molar mass = (78.8 g)/(18.0 g/mol) = 4.377 mol.
NH₄NO₃ → N₂O + 2H₂O,
It is clear that every 1.0 mole of NH₄NO₃ decomposes to 1.0 mole of N₂O and 2.0 moles of H₂O.
Using cross multiplication:
1.0 mole of NH₄NO₃ decomposes into → 2.0 moles of H₂O.
??? mole of NH₄NO₃ decomposes into → 4.377 moles of H₂O.
∴ The no. of moles of NH₄NO₃ that will produce 78.8 g of H₂O = (1.0 mol)(4.377 mol)/(2.0 mol) = 2.188 mol.
1.0 mole of NH₄NO₃ gives → - 77.4 kJ/mol.
∴ The heat evolved when 78.8 g of water is formed from this reaction = (no. of moles of NH₄NO₃)(heat evolved from decomposition of 1.0 mole of NH₄NO₃) = (2.188 mol)(- 77.4 kJ/mol) = - 169.42 kJ.
The study of chemicals and bonds is called chemistry. There are two types of elements in the periodic table and these are metals and nonmetals.
The correct answer is -169.42 kJ.
We have the enthalpy of reaction for the decomposition of ammonium nitrate, NH₄NO₃, which is - 77.4 kJ/mol. We need to calculate the no. of moles of NH₄NO₃ that will produce 78.8 g of H₂O.
Firstly, we need to calculate the no. of moles of 78.8 g of H₂O produced using the relation:
n = [tex]\frac{mass}{molar\ mass}[/tex]
n of H₂O = [tex]\frac{(78.8 g)}{(18.0)} = 4.377 mol.[/tex]
From the balanced equation of the decomposition of NH₄NO₃:
[tex]NH_4NO_3 ----> N_2O + 2H_2O,[/tex]
It is clear that every 1.0 mole of NH₄NO₃ decomposes to 1.0 moles of N₂O and 2.0 moles of H₂O.
Using cross multiplication:
1.0 mole of NH₄NO₃ decomposes into → 2.0 moles of H₂O.
The no. of moles of NH₄NO₃ that will produce 78.8 g of H₂O = (1.0 mol)
[tex]\frac{(4.377)}{(2.0)} = 2.188 mol.[/tex]
To get the heat evolved when 2.188 mol of NH₄NO₃ decomposed:
1.0 mole of NH₄NO₃ gives → - 77.4 kJ/mol.
The heat evolved when 78.8 g of water is formed from this reaction
= (no. of moles of NH₄NO₃)(heat evolved from the decomposition of 1.0 mole of NH₄NO₃)
= (2.188 mol)(- 77.4 kJ/mol) = - 169.42 kJ.
Hence, the correct answer is -169.42.
For more information about the decomposition reaction, refer to the link:-
https://brainly.com/question/16759172